Elastomers

Elastomers are dimensionally stable plastics that can, however, be elastically deformed when cold. These plastics play such an important role in today's industrial production that it is well worth taking a closer look at them:

  • What are elastomers?
  • What types of elastomers are there?
  • How do the different elastomers differ from each other?
  • What are the areas of application for elastomers?

In the following, we would like to give you a brief overview of the various elastomers, their manufacture and use, and illustrate the importance of elastomers for industry and production.

Elastomeric plastics can be reversibly molded

An elastomer is often referred to colloquially as rubber, regardless of its exact chemical structure. This linguistic inaccuracy is probably the result of the fact that all elastomers have a number of distinctive properties in common. This linguistic inaccuracy probably results from the fact that all elastomers have some distinctive properties in common:

  • Good moldability: an elastomer can be permanently molded into almost any desired shape during production.

  • High elasticity: Elastomers can be deformed under the action of force.

  • Good dimensional stability: If the applied force decreases, the elastomer returns to its original shape.

  • Thermoplasticity: Elastomers can be processed warm and shaped into the desired form.

  • Thermal stability: Elastomers can be used within a wide temperature range.

  • Chemical diversity and variability: Elastomers can be synthesized from a large number of chemical components. The composition of these components determines the physical properties of the later product. The inaccuracy is probably due to the fact that all elastomers have some distinctive properties in common:

  • Good formability: an elastomer can be permanently formed into almost any desired shape during production.

  • High elasticity: Elastomers can be deformed under the action of force.

  • Good dimensional stability: If the applied force decreases, the elastomer returns to its original shape.

  • Thermoplasticity: Elastomers can be processed warm and shaped into the desired form.

  • Thermal stability: Elastomers can be used within a wide temperature range.

  • Chemical diversity and variability: Elastomers can be synthesized from a large number of chemical components. Their composition determines the physical properties of the later product.

Its special mechanical properties make elastomer unique

Elastomers can be reversibly deformed under the action of mechanical force. Workpieces made of elastomer plastics can be stretched or squeezed. After the tensile or compressive load is removed, they return to their original shape. Only mechanical action is required for this deformation. The use of thermal energy is not necessary.

This special property is based on the wide-meshed linkage of the polymer chains within the plastic, which allows the chains to shift and move within certain limits. Once this limit has been exceeded, an effect occurs that can be mentally associated with a worn-out rubber band. Sealing washers and washers can also wear out under continuous load and eventually break.


Elastomers are characterized by high thermal resistance

Elastomers are dimensionally stable over a wide temperature range and retain their physical properties. Special adaptations in their chemical structure make it possible to produce special elastomers for low-temperature use. Likewise, it is possible to produce elastomers specifically for use in hot regions or production areas with high waste heat. Above the maximum operating temperature, elastomers can chemically decompose. Below the minimum operating temperature, they become brittle and lose their elastic properties.


What physical properties do elastomers have?

The most prominent property of elastomers is their ability to absorb tensile and compressive stresses. Two factors can affect the elasticity of such a plastic:

  • Cold causes elastomers to freeze glassy.
  • Heat does not cause classic elastomers to melt, but leads to their chemical decomposition.

What types of elastomers are there?

Elastomers are by no means limited to conventional rubber made from natural rubber. There is now a whole range of other plastics that, in addition to elasticity, have additional properties that can be used in industry:

  • Elastomers made from natural rubber
  • Elastomers made from synthetic rubber
  • Thermoplastic elastomers
  • Liquid crystalline elastomers (LCEs) Elastomers made from natural rubber

Elastomers made of natural rubber are characterized above all by high mechanical strength and elasticity. Their high resistance to abrasion should also be emphasized.

To date, natural rubber is an inexpensive material, but it has little resistance to UV radiation and ozone exposure. The resulting limitations in application led to the development of other elastomers.


Elastomers made from synthetic rubber

Elastomers made of synthetic rubber are very heterogeneous from a chemical point of view. They consist of two or more different monomers that are linked together in a chemical reaction - polymerization. The exact composition of these monomers influences the physical and resulting mechanical properties of the finished product. The most important synthetic rubbers include:

  • EPDM (ethylene-propylene-diene rubber) has good aging and acid resistance, but is not resistant to mineral oils.
  • SBR (styrene-butadiene rubber) has good abrasion resistance and electrical insulation properties.
  • IIR (butyl rubber)is characterized by good electrical insulating ability and low gas permeability.
  • IR (isoprene rubber) has excellent mechanical properties.
  • NBR (nitrile butadiene rubber) is used in hydraulics and pneumatics due to its resistance to mineral oils.

Thermoplastic elastomers (TPE)

Thermoplastic elastomers (TPE) combine the advantages of classic elastomers with those of thermoplastics. Thermoplastic elastomers behave like classic elastomers within the limits of their application temperature (usually in the range of room temperature). However, if they are exposed to heat, they begin to deform permanently. In this behavior, they resemble thermoplastics. Due to this property, TPEs can be welded, for example, to produce tight joints.


Liquid Crystalline Elastomers (LCEs)

Liquid crystalline elastomers (LCE) combine the high formability of elastomers with the tensile strength and electromechanical properties of liquid crystals. Thus, the shape of these plastics can be changed by applying an electrical voltage. Areas of application for LCEs include:

  • novel drive systems
  • soft contact lenses
  • active surfaces

These material types belong to the elastomers

Synthetic rubbers differ from one another, sometimes considerably, in terms of their physical properties. Commonly used synthetic rubbers include:

  • Acrylonitrile-butadiene rubber (NBR)
  • Ethylene-propylene-diene rubbers (EPDM)

As a flexible plastic, NBR can be adapted for specific purposes

Acrylonitrile-butadiene rubber is produced from the monomers acrylonitrile and 1,3-butadiene. The physical properties of the elastomer are determined by the mixing ratio. NBR is characterized by the following properties, among others:

  • good low-temperature resistance
  • wide thermal application range
  • good resistance to fuels and mineral oils

EPDM is characterized by high mechanical and thermal resistance

EPDM (ethylene-propylene-diene rubber) is a terpolymer of ethylene, propylene and any diene. This flexible chemical structure allows a wide range of variants. Consequently, EPDM can be used in a wide variety of applications. EPDM can be found in the following areas, among others:

  • Profiles for automotive construction
  • conveyor belts
  • hoses
  • pond liners

EPDM has good ozone and UV resistance. It also has high thermal resistance. The chemical resistance to polar solvents is very high, but non-polar solvents such as fuels and oils attack EPDM.

What distinguishes elastomers from thermoplastics

Thermoplastics can also be deformed, but thermal energy is required for this. Thermoplastics are therefore not suitable as spring and buffer elements. For a better comparison, two important thermoplastics are briefly presented:


PMMA is frequently used in outdoor

Polymethyl methacrylate (PMMA) is a thermoplastic also known as acrylic. PMMA is obtained by radical or anionic polymerization and then cast into crystal clear sheets.

PMMA is used in the following industries:

  • Automotive industry - turn signals and headlights
  • Aircraft construction - windows and headlights
  • Optics and lighting technology - lenses and illuminated signs
  • Medical technology - eyeglass lenses and dentures

Learn more about PMMA as a versatile thermoplastic here.


The high heat resistance makes POM a preferred plastic

Polyoxymethylenes (POM or also polyacetals) are thermoplastics that are mainly used for the production of molded parts by injection molding. POM is characterized by great hardness and rigidity.

Learn more about POM and its use here.


What are the differences between the various industrial rubbers?

Due to the different chemical structure, no two elastomers are alike. This feature enables their use in numerous industries:

  • EPDM has high resistance to weathering and ozone.
  • NBR is characterized by high mineral oil resistance and is suitable for allergy sufferers.
  • Silicone rubbers are food safe.
  • LCE are electrically conductive.

The different processes for the production of elastomers

Elastomers, like all plastics, consist of so-called polymers, i.e. long-chain molecules composed of one or more different monomers. The formation of such a polymer takes place in a polymerization reaction. These include:

  • Chain polymerization - Here, only one monomer is ever attached to the chain in each reaction step. No by-products are formed.
  • Polycondensation - In this polymerization, at least one by-product is formed.
  • Polyaddition - In such a reaction, low-molecular adducts also react with each other to form the finished product.

Elastomers are commonly used in these areas

There is hardly an area of application in modern industrial and manufacturing technology in which at least one elastomer does not play a prominent role. These include:

  • Automotive industry: seals, rubber lips and fuel lines are used in automobiles. Elastomers with high weather resistance and insensitivity to mineral oils are used primarily for this purpose.
  • Household: In households and offices, there is a great demand for low-cost elastomers, which are used, for example, as rubber rings.
  • Bathroom and sanitary installations: Elastomer sealing rings that are resistant to water and water vapor are used here.
  • Food production: Elastomers that are harmless to foodstuffs are used here in the form of seals and hose lines.
  • Medical technology: Elastomers in this area must be easy to sterilize and must not be allergenic.

Most common application: elastomers in automotive and tire construction

By far the largest share of global elastomer production is used for the manufacture of tires. Styrene-butadiene rubber (SBR) and butadiene rubber (BR), which are characterized by low abrasion and low costs, are used here in particular.


In what form are elastomers used in sports and household applications?

Yoga mats, shoe soles, bicycle tires - no modern sport would be possible without elastomers. The plastics used here must be low-wear and must not trigger any allergies.


Elastomers in other industrial and economic sectors

Dental technology, medical technology, molded part and prototype construction - hardly any branch of industry can do without specially developed elastomers. The main areas of application are where flexible connections, mechanical decoupling and sealing are required.

Find out now about the use of elastomers in the manufacture of our products

Sattler-scm has many years of experience and expertise in the development and production of elastomers. Besides sealing rings and bellows, silicone molded parts, rubber buffers and many more are part of our portfolio. If you have any questions about our products, please do not hesitate to contact us by phone or e-mail.

Dipl.-Ing. Thorsten Sattler-Lägel

As Managing Director of Sattler GmbH, it is a constant concern of mine to meet our customers not only as a trading partner, but also as a competent procurement service provider for applications in the plastics and rubber sector. I am an engineer by heart and most passionate when I can solve detailed technical issues to create sophisticated, customized solutions.

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